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DEAD is an aza-dienophile and an economical dehydrogenating agent, converting alcohols to aldehydes, thiols to disulfides and hydrazo groups to azo teams; It is usually a very good electron acceptor. Although DEAD is Employed in quite a few chemical reactions it is usually generally known as a critical ingredient with the Mitsunobu reaction, a typical system with the preparing of an amine, azide, ether, thioether, or ester through the corresponding Liquor.
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DEAD is actually a reagent within the Mitsunobu reaction wherever it forms an adduct with phosphines (normally triphenylphosphine) and assists the synthesis of esters, ethers, amines and thioethers from alcohols. Reactions normally result in the inversion of molecular symmetry.
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